The microstructure features of Ti-17 titanium alloy are very important to its
mechanical properties and high-temperature life. In this work, the effect of
compositional changes on the microstructure, hardness and oxidation resistance
and thermal shock behavior of Ti-17 alloys was thoroughly studied. Seven
compositions of Ti-17 alloy with various concentrations of Al, Mo, Cr and Zr were
successfully produced by powder metallurgy by powder mixing, cold compaction
and argon shielded sintering at 1500°C. The fabricated alloys were characterized
by X-ray diffraction (XRD), optical microscopy, scanning electron microscopy
(SEM) with energy-dispersive X-ray spectroscopy (EDX), Brinell hardness testing,
high-temperature oxidation tests at 600, 700 and 800°C, and thermal shock tests at
600 and 700°C. The findings showed that changes in the amounts of the alloying
elements had a considerable effect on the balance of the α/β phases and therefore
on the mechanical and thermal characteristics. Alloy No. 4(82Ti-2Sn-2Zr-5Al-
5Mo-4Cr) had the best overall performance of 402 HB, which was about 2.3%
higher than the typical Ti-17 alloy (396 HB). The alloy also displayed the lowest
oxidation weight increase at 800°C, suggesting better oxidation resistance owing
to the creation of a stable and adherent protective oxide layer and simultaneously
the strongest resilience to thermal shock under cyclic heating and cooling
circumstances. The better performance was due to the optimal balance of α- and
β-phase stabilizing elements, which resulted in a finer microstructure and
improved oxide-scale stability. These results demonstrate that the controlled
compositional optimization of Ti-17 alloys prepared by powder metallurgy is an
effective strategy to enhance hardness, oxidation resistance and thermal shock
resistance simultaneously, which makes the optimized alloy a promising
candidate for high-temperature aerospace and advanced engineering
applications.
Keywords: Ti-17, Oxidation, Thermal Shock, Microstructure
